AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process.

نویسندگان

  • Chengkou Liu
  • Zheng Fang
  • Zhao Yang
  • Qingwen Li
  • Shiyu Guo
  • Kai Guo
چکیده

An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 14 2  شماره 

صفحات  -

تاریخ انتشار 2016